Heterogeneously Catalyzed Aerobic Oxidation of Methane to a Methyl Derivative

نویسندگان

چکیده

A promising strategy to break through the selectivity-conversion limit of direct methane conversion achieve high yields is protection methanol via esterification a more stable methyl ester. We present an aerobic methane-to-methyl-ester approach that utilizes highly dispersed, cobalt-containing solid catalyst, along with significantly favorable reaction conditions compared existing homogeneously-catalyzed approaches (e.g. diluted acid, O2 oxidant, moderate temperature and pressure). The trifluoroacetic acid medium (<25 wt %) inert fluorous co-solvent can be recovered after separation trifluoroacetate liquid–liquid extraction at ambient conditions. Silica-supported cobalt catalysts are active in this system, competitive turnovers comparison known transition metal-based catalytic systems.

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ژورنال

عنوان ژورنال: Angewandte Chemie

سال: 2021

ISSN: ['1521-3773', '1433-7851', '0570-0833']

DOI: https://doi.org/10.1002/ange.202104153